Volume 102
Main Index

Issue 1, Pages 1-122 (2 December 1975)

Poly(methallyl alcohol)-supported rhodium hydrogenation catalysts Pages C12-C14 William R. Cullen, David J. Patmore, Angela J. Chapman and, Aubrey D. Jenkins

Spectrometrie de masse d'heterocycles des elements du groupe IV VI. interpretation automatique de spectre de masse de derives du silacyclopentadiene en vue de l'elucidation de leur structure Pages C7-C8 C. Lageot

Mechanism of nucleophilic addition to tricarbonyl (tropylium) cations of metals in group VI Pages C4-C6 K. M. Al-Kathum, L. A. P. Kane-Maguire

Erratum Page C15

Intramolekulare 1,3- und 1,4-protonverschiebung als sekundärreaktion bei der zersetzung von tetrahydrofuran durch benzyl- und phenyllithium Pages C1-C3 A. Maercker, J. Troesch

Untersuchungen zur reaktivität von metall-π-komplexen XX. nachweis der sterospezifischen ringprotonierung von nickelocen Pages C9-C11 G. K. Turner, W. Kläui, M. Scotti, H. Werner

Sur la stereochimie de la reaction entre le benzaldehyde et plusieurs α-bromosels en presene de zinc: Influence de divers facteurs Pages 1-5 Moncef Bellassoued, Marcel Gaudemar

Organoelemental Fragmentations : II. A proof of tautomeric arene intermediates in reactions of organometallic benzyl compounds with acids. Aromatisational mercuration of 1-methylene-2,4-cyclohexadiene Pages 7-11 V. I. Rozenberg, V. A. Nikanorov, V. I. Salikova, Yu. G. Bundel' and, O. A. Reutov

Oxidation metallorganischer verbindungen : I. Zur oxidation isomerer diibutylaluminium-n-hexanolate Pages 13-19 Günter Schmitt

Tri-t-butylsilane: synthesis, physical properties, derivatives, and reactivity towards ozonolysis, chlorination, fluorination, and hydrolysis Pages 21-27 Edward M. Dexheimer, Leornard Spialter, Lee D. Smithson

Difunctional derivatives of hexaphenyldisiloxane Pages 29-39 L. W. Breed, J. C. Wiley Jr.

Chloride for bromide substitutions on carbon utilizing tri-n-butyltin chloride Pages 41-48 Edwin C. Friedrich, Paul F. Vartanian, Roy L. Holmstead

Derivatives of cycloheptatrienylcyclopentadienyltitanium Pages 49-56 H. T. Verkouw, M. E. E. Veldman, C. J. Groenenboom, H. O. Van Oven, H. J. De Leifde Meijer

Preparation of new alkychromium complexes RCrCl2(BASE)n (R = CH3, C2H5) and effects of the base on their thermal stability Pages 57-63 Akio Yamamoto, Yoshio Kano, Takakazu Yamamoto

Quantum yield for the photosubstitution of a carbonyl group in mesitylenechromium tricarbonyl by a maleimide Pages 65-70 J. Nasielski, O. Denisoff

The addition of carbon monoxide to certain binuclear organometalllic compounds of iron, molybdenum and tungsten containing bridging thiolate ligands. The formation fo mononuclear species Pages 71-77 Darrell D. Watkins Jr., T. Adrian George

Etude structurale de ferrocenophanes I. Structure cristalline et moleculaire du (cyclopentylene-1″,3″)-1,1′ ferrocene Pages 79-91 Patrick Batail, Daniel Grandjean, Didier Astruc and, Rene Dabard

The nature of cobalt species formed during the reaction of cobalt(III) acetylacetonate with triisobutylaluminium in aromatic hydrocarbons under hydrogen Pages 93-107 S. Tyrlik, M. Michalski

Die kristall- und molekularstruktur von (CO)9Co3COBCl2N(C2H5)3 Pages 109-117 Volker Bätzel, Ulrich Müller, Rudolf Allman

Intermolecular interactions in tetrakis(arylisonitrile)-platinum(II) tetracyanoplatinate(II) Pages 119-122 H. J. Keller, R. Lorentz

Issue 2, Pages 123-263 (9 December 1975)

Hyperconjugation and homoconjugation in alkyl radicals bearing β-phosphorus substituents Pages C17-C19 Ian G. Neil, Brian P. Roberts

The stereochemistry of the β elimination of β-trimethylsiloxy organoboranes Pages 123-127 Gerald L. Larson, Antonio Hernández

Enolates d'esters : V. Preparation des analogues lithiens des reactifs de reformatsky a partir des esters α,α-dichlores et α-monohalogenes. Reactivite Pages 129-140 Jean Villieras, Pierre Perriot, Monique Bourgain, Jean-F. Normant

Some reactions of arsonium ylides involving transylidation Pages 141-143 P. S. Kendurkar, R. S. Tewari

Palladium(II)chlorid-komplexe von silylierten thiazol-, imidazol- und pyridinderivaten Pages 145-152 Peter Jutzi, Hermann Heusler

Essais d'analyse conformationnelle de cyclopentanols et de germacyclopentanols Pages 153-159 Alain Lectard, Cambize Vaziri, Jean-Claude Richer, Jean-Claude Florence and, Georges Manuel

Mechanistic aspects of the thermal decomposition of dicyclopentadienyltitanium(IV)diaryl compounds Pages 161-165 C. P. Boekel, J. H. Teuben, H. J. de Liefde Meijer

Polypyrazolylborate complexes of titanium and vanadium Pages 167-174 Leo E. Manzer

Synthesis of α-methylene-γ-butyrolactone via transition metal carbene complexes Pages 175-183 Charles P. Casey, William R. Brunsvold

Arenetricarbonyl-molybdenum and -tungsten complexes Pages 185-193 A. N. Nesmeyanov, V. V. Krivykh, V. S. Kaganovich, M. I. Rybinskaya

The origin of some irreproducibilities in the kinetic study of the reaction W(CO)5 (aniline) + P(C6H5)3 Pages 195-198 J. Nasielski, M. Vermeulen, P. Leempoel

Reactions of manganese and rhenium halogenopentacarbonyls with 1,2-dicyanobenzene Pages 199-203 J. G. Dunn, D. A. Edwards

Austauschreaktionen an komplexgebundenen liganden von elementen der IV. Hauptgruppe : III. Darstellung von halogen-, pseudohalogen- und hydridokomplexen des typs π-C5H5Fe(CO)2SiX3 Pages 205-211 Mathias Höfler, Jürgen Scheuren, Detlef Spilker

Electron spin resonance studies of an iron nitroxide, [(CN)5FeN.(Ph)OH]3− and some related radicals Pages 213-218 Martyn C. R. Symons, Douglas X. West, James G. Wilkinson

Ferrocene polymers. Synthesis and thermal polymerization of α-chloro-β-formyl-p-ferrocenylstyrene Pages 219-226 Cr. Simionescu, Tatiana Lixandru, Lucia Ttaru, I. Mazilu, I. Cocîrl

The vibrational spectra of complexes of norbornadiene with some group VIII metals Pages 227-238 I. A. Zakharova, Ya. V. Salyn, I. A. Garbouzova, V. T. Aleksanyan and, M. A. Prianichnicova

Orientation de la palladation du noyau naphtalenique dans les α et β dimethylaminomethyl naphtalenes Pages 239-243 M. Julia, M. Duteil, J. Y. Lallemand

Studies on metal—acetylene complexes : VI. Crystal and molecular structure of [diethylbis(1-pyrazolyl)borato]methyl(1-phenylpropyne)-platinum(II), [(C2H5)2B(N2C3H3)2](CH3)Pt(C6H5CCCH3) Pages 245-257 Brian William Davies, Nicholas C. Payne

Preparation and some reactions of tris(polychlorophenyl)thallium(III) compounds Pages 259-263 Shigeaki Numata, Hideo Kurosawa, Rokuro Okawara

Issue 3, Pages 265-406 (16 December 1975)

Some unexpected reactions of perfluoroalkynylmagnesium halides Pages C21-C24 G. Santini, M. Le Blanc, J. G. Riess

Synthese et configuration absolue d'enantiomeres silicies bifonctionnels Pages C25-C28 R. J. P. Corriu, F. Larcher, G. Royo

Selektive hydrierung von mesityloxid zum methylisobutylketon mit dem katalysator-system RhCl(PPh3)3 + H2O2 bei umsatzzahlen von über 100 000 ohne solvens Pages C37-C41 Walter Strohmeier, Erich Hitzel

The hydropalladation reaction Pages C34-C36 Derek J. Mabbott, Peter M. Maitlis

A novel synthesis and X-ray structure of a new aryldiazene complex: trans-(phenylacetylide)bis(triphenylphosphine)(p-fluorophenyldiazene)platinum(II) tetrafluoroborate Pages C31-C33 U. Croatto, L. Toniolo, A. Immirzi, G. Bombieri

The nature of bridging and semi-bridging carbonyl groups Pages C29-C30 David A. Brown, Noel J. Fitzpatrick, A. R. Manning

Sur le mecanisme de decomposition des organothalliques, (CH3)2C(OX)---CH2Tl(OAc)2, en milieu aqueux Pages 265-271 Charles Beaudry, Miklos Zador

Flash photolysis of tetraethyltin and tetravinyltin Pages 273-290 M. Christianson, D. Price, R. Whitehead

Organozinnverbindungen : XXVII. Über cyclopentadienylzinn(IV)-halogenide und ihre komproportionierungsreaktionen Pages 291-295 Ulrich Schröer, Hans-Joachim Albert, Wilhelm P. Neumann

Conformational consequences of metallo-methyl interactions: A 13C nuclear magnetic resonance study Pages 297-311 W. Adcock, B. D. Gupta, W. Kitching, D. Doddrell

Photoelectron spectroscopy study of the triphenyl derivatives of the group V elements Pages 313-316 G. Distefano, S. Pignataro, L. Szepes, J. Borossay

Mechanistic aspects of the thermal decomposition of dicyclopentadienyltitanium(IV) dibenzyl Pages 317-320 C. P. Boekel, J. H. Teuben, H. J. De Liefde Meijer

Stability and bond strength in adducts of mercury(II) halides with transition metal carbonyl derivatives Pages 321-326 D. P. Graddon, I. K. Gregor, I. A. Siddiqi

Electrochemical measurements as a probe for the investigation of the structure of metal carbonyls Pages 327-333 C. J. Pickett, D. Pletcher

The photochemical synthesis of (Et4N)[Mn2(CO)6μ-Cl)3] Pages 335-337 John L. Cihonski, Michael L. Walker, Robert A. Levenson

Jahn---Teller effects in metallocenes and related species Pages 339-343 C. Glidewell

Synthesis and structure proof of a new ring system from the reaction of diironnonacarbonyl and naphtho[b]-cyclopropene Pages 345-351 F. A. Cotton, J. M Troup, W. E. Billups, L. P. Lin and, C. V. Smith

Activation d'agents reducteurs: “reducteurs complexes” contenant NaH , : II. Reduction de derives gem dihalogeno cyclopropaniques Pages 353-363 G. Guillaument, L. Mordenti, P. Caubere

Palladium(II), platinum(II) and mercury(II) complexes of ambidentate phosphonium, arsonium, sulfonium and pyridinium ylids Pages 365-385 Edward T. WeleskiJr., Joel L. Silver, Muriel D. Jansson, John L. Burmeister

Olefin complexes of rhodium(I) containing the ligands but-3-enyldiphenylphosphine and diphenylpent-4-enylphosphine Pages 387-396 P. W. Clark, G. E. Hartwell

Carbene complexes from the reaction of ionic isocyanide complexes of gold(I) with alcohols and amines Pages 397-406 Giovanni Minghetti, Luciano Baratto, Flavio Bonati

Issue 4, Pages 407-563 (23 December 1975)

Scandium Its Occurrence, Chemistry, Physics, Metallurgy, Biology and Technology : by C.T. Horovitz (Editor), K.A. Gschneidner Jr., G.A. Melson, D.H. Youngblood and H.H. Schock, Academic Press, London, 1975, 598 pages, £16.00, $42.25. Page C52 M. F. Lappert

Erratum Page C54

Strength of the Pt---CS2 bond in Pt(PPh3)2(CS2) Pages C43-C45 C. T. Mortimer, M. P. Wilkinson, R. J. Puddephatt

The reaction of allene with β-diketonatoiridium(I) complexes: formation and crystal structure of a new bis-β-allylic derivative of iridium(III) Pages C49-C51 P. Diversi, G. Ingrosso, A. Immirzi and, M. Zocchi

Synthesis of a transition metal-dithionite complex, (η5-C5H5)(CO)2Fe---S(O)2S(O)2---Fe(CO)2(η5-C5H5) Pages C46-C48 Norman H. Tennent, Sophia R. Su, Craig A. Poffenberger, Andrew Wojcicki

Catalysis: Heterogeneous and Homogeneous : edited by B. Delmon and G. Jannes, Elsevier Scientific Publishing Company, Amsterdam and New York, 1975, xxvi + 550 pages, $45.95, Dfl. 110.00. Pages C52-C53 M. F. Lappert

Mechanism of nucleophilic substitution at silicon: kinetic evidence on the slow formation of a pentacoordinate silicon intermediate Pages 407-416 Robert J. P. Corriu, Bernard J. L. Henner

Reactivity of main group---transmittion metal bonds : III. Reactions of halogens with Ph3SiMn(CO)5 and Ph3SnMn(CO)5 Pages 417-421 J. R. Chipperfeld, J. Ford, D. E. Webster

Un nouvel aspect de la reactivite des trihalogenomethyltrialkyletains: l'addition aux aldehydes Pages 423-430 Christian Furet, Christian Servens, Michel Pereyre

Direct synthesis of mixed methylethyllead alkyls Pages 431-436 K. Jaworski, L. Wilkanowicz, A. Kunicki

(Halomethyl)arsenic compounds : I. Synthesis and characterization of (chloromethyl)arsine Pages 437-444 Arnold L. Rheingold, Jon M. Bellama

(Halomethyl)arsenic compounds : II. Preparation and dynamic NMR spectra of pentakis(chloromethyl)cyclopentaarsine Pages 445-455 Arnold L. Rheingold, Jon M. Bellama

The crystal and molecular structure of bis(pentamethylcyclopentadienyl)dichlorotitanium(IV) Pages 457-466 Thomas C. McKenzie, Robert D. Sanner, John E. Bercaw

Crystal and molecular structure of two monoclinic forms of tricarbonyldiiodo[bis(dimethylphosphine)ethane]-tungsten(II) Pages 467-480 Michael G. B. Drew, Colin J. Rix

Spectres de vibration et champs de force de valence de quelques composes π benzoate de methyle Cr(CO)3-nLn : II. Benzoate de methyle chrome tricarbonyle Pages 481-490 P. Caillet

Gehinderte Ligandenbewegungen in Übergangsmetallkomplexen : VII. Rotation der olefinliganden L = malein- und furmarsäuredimethylester in komplexen des typs C5H5Mn(CO)2L und C5H5Cr(CO)(NO)L Pages 491-505 Helmut Alt, Max Herberhold, Cornelius G. Kreiter, Hans Strack

Synthetic studies relating to acetylergosterol-(tricarbonyl)iron Pages 507-510 Graham Evans, Brian F. G. Johnson, Jack Lewis

Transition metal---carbon bonds : XL. Palladium(II) complexes of [(dimethylamino)methyl]-ferrocene Pages 511-516 John C. Gaunt, Bernard L. Shaw

Transition metal---carbon bonds : XLI. Internal metallation reactions of palladium(II)-t-butyldibenzylphosphine and —benzyldi-t-butylphosphine complexes Pages 517-525 Bernard L. Shaw, Margaret M. Truelock

Darstellung von cis-tetrahalogenodicarbonylosmaten(II) durch decarbonylierung ungesättigter alkohole Pages 527-534 F. H. Johannsen, W. Preetz, A. Scheffler

Basicity of transition metal carbonyl complexes : VIII. An infrared study of the reaction of aluminium chloride with some cyclopentadienyl and arenecarbonyl transition metal complexes Pages 535-542 B. V. Lokshin, E. B. Rusach, Z. P. Valueva, A. G. Ginzburg, N. E. Kolobova

Homogeneous Catalysis : III. Hydrosilylation of α,β-unsaturated aldehydes; regiospecific reduction of C=O using Ni0 catalysts Pages 543-550 M. F. Lappert, T. A. Nile

Group IB organometallic chemistry : XVI. Complex formation between 2-(dimethylamino)-phenylcopper with copper(I) or silver halides. Synthesis and structural characterization of hexanuclear (2-Me2NC6H4)4Cu6-nMnX2 (M = Cu or Ag) cluster compounds Pages 551-563 Gerard van Koten, Jan G. Noltes